Synthesis of polyvinyl pyridine/C60 conjugates in supercritical carbon dioxide*
نویسندگان
چکیده مقاله:
In the present investigation efforts have been made to synthesis polyvinyl pyridine (PvPy) /C60 conjugates through 2, 2-azobisisobutyronitrile (AIBN) initiated insitu polymerization of PvPy in scCO2.The process of synthesis was monitored under different reaction conditions ranging 1200-1800psi, 60-90 oC over 6 hours. The progress of polymerization was monitored rheoviscometrically. The concentration of PvPy and AIBN ranging 6.95-20.85*10-3 and 304.50-931.50 *10-3 afforded PvPy/C60 conjugates in the yield (%) ranging 10.30-48.8. Selected PvPy/C60 conjugates were characterized through UV-VIS spectra, scanning electron microscopy, gel permeation chromatography and solution rheoviscometery.
منابع مشابه
synthesis of polyvinyl pyridine/c60 conjugates in supercritical carbon dioxide*
in the present investigation efforts have been made to synthesis polyvinyl pyridine (pvpy) /c60 conjugatesthrough 2, 2-azobisisobutyronitrile (aibn) initiated insitu polymerization of pvpy in scco2.the processof synthesis was monitored under different reaction conditions ranging 1200-1800psi, 60-90 oc over 6hours. the progress of polymerization was monitored rheoviscometrically. the concentrati...
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عنوان ژورنال
دوره 3 شماره 1
صفحات 63- 68
تاریخ انتشار 2007-12-01
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